Acknowledgments vii 1 Introduction 1 2 Marcus Theory of Electron Transfer 5 3 Photosynthetic Reaction Center Models 7 4 Electron Donor-Acceptor Dyads 11 5 Supramolecular Electron Transfer 25 5.1 Cation-Anion Binding 25 5.2 Ï-Complexes 35 5.3 Electron-Transfer Switching 46 5.4 Dendrimers 53 5.5 Supramolecular Solar Cells 55 6 Effects of Metal Ions on Photoinduced Electron Transfer 65 7 Photoredox Catalysis 69 7.1 Photocatalytic Oxygenation 69 7.2 Photocatalytic Oxibromination 77 7.
3 Carbon--Carbon Bond Formation 77 7.4 DNA Cleavage 81 7.5 Anti-Markovnikov Hydroetherification 81 7.6 Photocatalytic Cycloaddition 83 7.7 Photocatalytic Hydrotrifluoromethylation 85 7.8 Photocatalytic Hydrogen Evolution 86 8 Hydrogen Storage 93 8.1 Interconversion Between Hydrogen and Formic Acid 95 8.2 Interconversion Between Hydrogen and NADH 101 8.
3 Hydrogen Evolution from Alcohols 104 8.4 Hydrogen Evolution from Paraformaldehyde 107 9 Metal Ion-Coupled Electron Transfer (MCET) 109 9.1 MCET of O2 109 9.2 Binding Modes of Metal Ions 114 9.3 Self-Organized MCET 124 9.4 Accelerating and Decelerating Effects of Metal Ions 132 9.5 Driving Force Dependence of MCET Rate Constants 137 9.6 MCET Coupled with Hydrogen Bonding 143 9.
7 MCET Catalysis 148 9.7.1 Hydride Transfer vs. Cycloaddition 148 9.7.2 Suproxode Disumutase (SOD) Models 152 9.8 MCET of Metal-Oxo Complexes 157 9.9 PCET of Metal-Oxo Complexes 162 9.
10 Unified Mechanism of MCET and PCET of Metal-Oxo Complexes 165 9.11 MCET of Metal-Peroxo Complexes 169 10 Catalytic Reduction of O2 173 11 Catalytic Oxidation of H2O 181 12 Production of Hydrogen Peroxide from Water and Oxygen as a Solar Fuel 187 13 Production and Usage of Hydrogen Peroxide as a Solar Fuel in Seawater 193 14 Photosystem II Mimic 197 15 Conclusion and Perspective 201 References 203 Index 225.