1. Introduction This chapter is to introduce the development of silver catalysis and its history. 2. Radical reactions 2.1 Introduction 2.2 Radical phosphinylation 2.3 Radical cyclization 2.4 Radical addition 2.
5 Radical Azidation 2.6 Conclusion 3. Activation of carbon-carbon triple bonds 3.1 Introduction 3.2 Formation of Carbon-Carbon Bonds 3.2.1 Alkynylation 3.2.
1.1 Formation of Csp-Csp bonds 3.2.1.2 Formation of Csp2-Csp bonds 3.2.1.3 Formation of Csp3-Csp bonds 3.
2.2 Cycloaddition and cyclization 3.2.3 Reactions via arynes 3.2.4 Cycloisomerization 3.2.5 Carbenoids 3.
3 Formation of Carbon-Nitrogen Bonds 3.3.1 Intermolecular hydroamination 3.3.2 Intramolecular hydroamination 3.3.3 Cyclization 3.3.
4 Cycloaddition 3.3.5 Azidation 3.3.6 Multicomponent Reactions 3.4 Formation of Carbon-Oxygen Bonds 3.4.1 Hydrofunctionalization 3.
4.2 Carbonyl-yne cycloisomerization 3.4.3 CO2 incorporation 3.4.4 Miscellaneous reactions 3.5 Formation of carbon-X bonds 3.5.
1 Formation of carbon-halogen bonds 3.5.2 Formation of Carbon-Sulfur Bonds 3.5.3 Formation of Carbon-Phosphorus Bonds 3.5.4 Formation of Carbon-Boron Bonds 3.6 Conclusion 4.
C-H bond functionalization 4.1 Introduction 4.2 bond arylation 4.3 C-H Bond Phosphorylation 4.4 C-H bond sulfenylation 4.5 C-H Fluorination and C-H trimethylfluorination 4.6 Enantioselective C-H Activation 4.7 Conclusion 5.
Aldol reactions 5.1 Introduction 5.2 Aldol Reactions of Isocyanoacetates 5.3 Mannich reaction 5.4 Nitroso Aldol reaction 5.5 Conclusion 6. Coupling reactions 6.1 Introduction 6.
2 C-C bond coupling 6.2.1 Homocoupling 6.2.2 Cross coupling 6.2.3 Oxidative cross coupling 6.2.
4 Sonogashira coupling 6.3 C-heteroatom coupling 6.3.1 C-N bond coupling 6.3.2 C-O bond coupling 6.3.3 C-S , C-Se bond coupling 6.
3.4 C-P bond coupling 6.4 Conclusion 7. Cycloaddition reactions 7.1 Introduction 7.2 [3+2] cycloaddition 7.2.1 [3+2] Cycloaddition of Azomethine Ylides 7.
2.2 Other [3+2] Cycloadditions 7.2.3 1,3-Dipolar Cycloaddition 7.3 [2+2] Cycloadditions 7.4 [3+3] Cycloaddition 7.5 [4+2] Cycloaddition 7.6 Conclusion 8.
Rearrangement reactions 8.1 Introduction 8.2 Wolff rearrangement 8.3 Ring rearrangement 8.4 Enolate Claisen Rearrangement 8.5 [1,2]-Sigmatropic rearrangement 8.5.1 1,2-Migration 8.
5.2 1,4-Migration 8.6 Conclusion 9. Asymmetric synthesis 9.1 Introduction 9.2 Asymmetric Reactions 9.2.1 Cycloaddition Reactions 9.
2.1.1 [3+2] Cycloaddition 9.2.1.2 Hetero-Diels-Alder Reaction 9.2.1.
3 [2+2] Cycloaddition 9.2.2 BINAP-Ag(I) Catalytic System 9.2.2.1 Allylation Reaction 9.2.2.
2 Mukaiyama-Aldol Reaction 9.2.2.3 Nitroso-Aldol Reaction 9.2.2.4 Protonation of Silyl Enolates 9.2.
3 Amino Acid Derived Phosphine-Ag(I) Catalyst 9.2.3.1 Mannich Reaction 9.2.4 Group-Transfer Reactions 9.2.4.
1 Carbene-Transfer Reactions 9.2.4.2 Nitrene-Transfer Reaction 9.2.4.3 Silylene-Transfer Reaction 9.3 Conclusion 10.
Carbene, nitrene, silylene transfer reactions 10.1 Introduction 10.2 Carbene transfer reactions 10.2.1 Carbene Transfer Reactions to p Bonds 10.2.1.1 Aziridination 10.
2.1.2 Cyclopropanation 10.2.2 Formation and Reactions of Ylides 10.2.2.1 C-Hal Addition-Rearrangement Reactions 10.
2.2.2 C-S Addition-Rearrangement Reactions 10.2.3 C-H Insertion 10.2.4 N-H Insertion 10.2.
5 Ring Expansion Reactions 10.2.6 Intermediacy of Silver Carbenes 10.2.7 Miscellaneous Reactions Involving Silver Carbenoids 10.3 Nitrene transfer reactions 10.3.1 Aziridination 10.
3.1.1 Iminoiodanes as Nitrene Precursors 10.3.1.2 Chloramine-T as Nitrene Precursor 10.3.2 Sulfide and Sulfoxide Imination 10.
3.3 Amidation 10.3.3.1 Intramolecular Amidation 10.3.3.2 Intermolecular Amination with Phenanthroline Ligands 10.
3.3.3 Intermolecular Amination Based on Pyrazolylborate Ligands 10.4 Silylene transfer reactions 10.4.1.